Cat#: CCR-0252
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Synonyms (s): (R,R)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,O′-(2,2′-Biphenyldiyl) N,N-bis[(R)-1-phenylethyl]phosphoramidite, BIPOL-A1(R)
Empirical Formula (Hill Notation): C28H26NO2P
Size: 100 mg; 500 mg
Product Introduction
Molecular Weight | 439.49 |
NACRES | NA.22 |
CAS Number | 500103-26-4 |
MDL Number | MFCD08277032 |
PubChem Substance ID | 329747990 |
Assay | ≥99.0% |
Reaction Suitability | Reaction type: click chemistry |
Smiles String | C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5 |
InChI | 1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3 |
InChI key | JISGHECLGYELKD-UHFFFAOYSA-N |
Application
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:In the asymmetric hydrovinylation of 1,3-diene.In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.
Safety Information
Storage Class Code | 13 - Non Combustible Solids |
WGK | WGK 3 |
For research use only. Not for clinical use.