Hydroxy[-(S)-BINAP]-rhodium(I) Dimer

Empirical Formula (Hill Notation): C₈₈H₆₆O₂P₄Rh₂

Size: 250 mg

Product Introduction

Molecular Weight	1485.17
NACRES	NA.22
MDL Number	MFCD08561132
PubChem Substance ID	24884495
Assay	90%
Form	Solid
Reaction Suitability	Reaction type: click chemistry
Smiles String	[H]O[Rh].[H]O[Rh].c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8.c9ccc(cc9)P(c%10ccccc%10)c%11ccc%12ccccc%12c%11-c%13c(ccc%14ccccc%13%14)P(c%15ccccc%15)c%16ccccc%16
InChI	1S/2C44H32P2.2H2O.2Rh/c21-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;;/h21-32H;21H2;;/q;;;;2+1/p-2
InChI key	PWIUOLBVYNHREE-UHFFFAOYSA-L

Application

Efficient and Selective Catalysts for Asymmetric Synthesis
Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones. Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.

Safety Information

Signal Word	Warning
Hazard Classifications	H351
Storage Class Code	13 - Non Combustible Solids
WGK	WGK 3

For research use only. Not for clinical use.